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祝贺吴华悦和刘妙昌老师指导研究生在advanced synthesis & catalysis发表学术论文 | |||
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日期:2018-10-11阅读:次 | |||
标题:silver-catalyzed one-pot three-component selective synthesis of β-hydroxy selenides abstract: a convenient, multi-component reaction of organoboronic acids, selenium powder and epoxides has been developed, providing an efficient protocol for the synthesis of β-hydroxy selenides with excellent selectivity and good functional group tolerance. preliminary mechanistic studies suggest that the reaction proceeds through the silvercatalyzed radical selenation of the arylboronic acids to generate a diselenide, and subsequent selenium-mediated selective ring-opening arylselenation of epoxides.
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